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We have demonstrated a novel method to convert benzene derivatives to high-value polyunsaturated acyclic molecules, which involves an unusual mechanism with carbene intermediates.
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Herein, we develop an EDA complex photocatalytic system through rational design, which overcomes the oxygen-sensitive limitation of traditional EDA photocatalytic systems and enables aerobic oxygenation reactions through dioxygen activation.
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We report a catalytic aerobic oxidative approach for polyolefins upcycling with the corresponding carboxylic acids as the product. This method encompasses three key innovations